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Manufacture-affected asphaltene genesis in dispersion hardened bitumen-mineral compositions

https://doi.org/10.31675/1607-1859-2022-24-5-178-188

Abstract

   The paper focuses on increasing the service life of the road pavement layers made of dispersion hardened organomineral mixtures through the aging intensity reduction of organic binder, which begins at the preparation stage of these mixtures and lasts during the structural layer operation.

   The organic binder generates adsorption-volute shells on the surface of mineral materials, which become more viscous and acquire increased brittleness. Crack formation becomes more intensive, pavement designed and built in accordance with the requirements destroys. Dispersion hardening of the pavement structural layers with chemical fibers from spent sorbents containing oil products, can be used to partially solve this problem.
   The purpose of the work is to study the aging intensity of the binder in organomineral mixtures using electron paramagnetic resonance methods.

   The aging intensity of the organic binder is evaluated by the concentration of paramagnetic centers, since asphaltenes are almost one hundred percent concentrate of paramagnets, which can serve as an indicator of the aging intensity of the petroleum dispersion system. It is shown that dispersion hardening of the pavement layers by chemical fibers from spent sorbents containing absorbed oil products, decreases the concentration of paramagnetic centers, which indicates to the higher concentration of asphaltenes, which, in turn, means a decrease in the aging intensity of the oil dispersion system.

About the Authors

V. N. Lukashevich
Tomsk State University of Architecture and Building
Russian Federation

Viktor N. Lukashevich, DSc, Professor

634003

2, Solyanaya Sq.

Tomsk



O. D. Lukashevich
Tomsk State University of Architecture and Building
Russian Federation

Olga D. Lukashevich, DSc, Professor

634003

2, Solyanaya Sq.

Tomsk



R. I. Mokshin
Tomsk State University of Architecture and Building
Russian Federation

Roman I. Mokshin, Research Assiatnt

634003

2, Solyanaya Sq.

Tomsk



References

1. Gezentsvei L. B., Sliva G. Ya. Izbiratelnaya filtraciya bitumov pri vzaimodejstvii s mineralnymi poroshkami. [Selective filtration of bitumen in interacting with mineral powders]. Trudy Soyuzdornii. 1971. V. 44. Pp. 98−105. (rus)

2. Gezentsvei L. B. (Ed.), Gorelyshev N. V., Boguslavsky A. M., Korolev I. V. Dorozhnyj asfal'tobeton [Asphalt concrete]. 2nd ed., Moscow: Transport, 1985. 350 p. (rus)

3. Gezentsvei L. B., Kolbanev I. V., Rvacheva E. M. Mekhano-khimicheskie protsessy v bitumomineral'nykh sistemakh [Mechano-chemical processes in bitumen mineral systems]. Avtomobilnye dorogi. 1971. Nо 2. Р.6–9. (rus)

4. Babaev V. I. Starenie asfal`tobetona v usloviyax yuga Rossii [Aging of asphalt concrete in the south of Russia]. Avtomobilnye dorogi. 1994. Nо. 3. P. 21. (rus)

5. Bakhrakh G. S. Otsenka termookislitel'noi stabil'nosti asfal'tovykh materialov s uchetom roli kontaktnykh vzaimodeistvii [Assessment of thermal-oxidative stability of asphalt materials and the role of contact interactions]. Trudy Soyuzdornii. 1975. V. 79. Pp. 132–140. (rus)

6. Davydova A. R., Gladyr S. A., Telkova T. N. Issledovanie izmenenij, protekayushhix v bitumax pri ix glubokom okislenii [Study of changes in bitumen during deep oxidation]. Trudy Soyuzdornii. 1977. V. 100. Pp. 4–12. (rus)

7. Davydova A. R. Issledovanie processa stareniya bituma pod vliyaniem razlichnyx faktorov [Bitumen aging process under the influence of various factors]. Trudy Soyuzdornii. 1971. V. 44. Pp. 48–54. (rus).

8. Grushko I. M., Korolev I. V., Borshh I. M., Mishhenko G. M. Dorozhno-stroitel`nye materialy [Road building materials]. Moscow: Transport, 1983. 129 p. (rus)

9. Melentev V. A. Sostav i svojstva zoly i shlaka TETz: Spravochnoe posobie [Composition and properties of ash and slag from thermal power plants: Reference guide]. Moscow: Energoizdat, 1985. 285 p. (rus)

10. Metodicheskie rekomendacii po texnologii primeneniya v asfal`tobetone otval`nyx zoloshlakovyx smesej teploe`lektrostancij [Guidelines for using waste ash and slag mixtures from thermal power plants in asphalt concrete]. Moscow: SoyuzdorNII, 1978. 23 p. (rus)

11. Chistyakov B. Z., Lyalinov A. N. Ispol`zovanie mineral`nyx otxodov promy`shlennosti [Industrial mineral waste application]. Leningrad: Stroiizdat, 1984. 150 p. (rus)

12. Lesueur D. The colloidal structure of bitumen: Consequences on the rheology and on the mechanisms of bitumen modification. Advances in Colloid and Interface Science. 2009. No. 145 (1-2). Pp. 42–82.

13. Sá da Costa M., Farcas F., Santos L. F., Eusébio M. I., Diogo A. S. Chemical and thermal characterization of road bitumen ageing. Materials Science Forum. 2011. V. 636–637. Pp. 273–279. https://doi.org/10.4028/www.scientific.net/MSF.636-637.273

14. Petersen J. Chemical composition of asphalt as related to asphalt durability: state of the art. Washington: Transportation Research Board, 1984. Pp. 13–30.

15. Petersen J. A review of the fundamentals of asphalt oxidation: chemical, physicochemical, physical property, and durability relationships. Transportation Research E-Circular (Vol. 1). Transportation Research Board. 2009. 68 p.

16. Siddiqui M. N., Ali M. Studies on the aging behavior of the Arabian asphalts Siddiqui. Fuel. 1999. No. 78 (9). Pp. 1005–1015.

17. Siddiqui M. N., Ali M. Investigation of chemical transformations by NMR and GPC during the laboratory aging of Arabian asphalt. Fuel. 1999. No. 78 (12). Pp. 1407–1416.

18. Qi Y., Wang F. Study and evaluation of aging performance of petroleum asphalts and their constituents during oxygen absorption. I. Oxygen absorption behaviors and kinetics. Petroleum Science and Technology. 2003. V. 21(1). Pp. 283–299.

19. Qi Y., Wang F. Study and evaluation of aging performance of petroleum asphalts and their constituents during oxygen absorption. II. Chemical group composition and structure changes. Petroleum Science and Technology. 2004. V. 22 (3). Pp. 263–274.

20. Qi Y., Wang F. Study and evaluation of aging performance of petroleum asphalts and their constituents during oxygen absorption. III. Average molecular structure parameter changes. Petroleum Science and Technology. 2004. V. 22 (3). Pp. 275–286.

21. Reyes F. A., Daza C. E., Rondon H. A. Determination of SARA fractions of environmentally aged Colombian asphalts using liquid chromatography column. Revista EIA. 2012. V. 17. Pp. 47–56.

22. Glotova N. A., Gorshkov V. S., Kats B. I. Izmenenie reologicheskikh svoistv i khimicheskogo sostava bitumov pri starenii [Changes in rheological properties and chemical composition of bitumen during aging]. Khimiya i tekhnologiya topliv i masel. 1980. No 4. Pp. 47–49. (rus)

23. Slobodchikov Yu. V. Issledovanie vliyaniya uslovij e`kspluatacii na nadezhnost` bitumo-mineral`ny`x pokry`tij avtomobil`ny`x dorog Severnogo Kazaxstana: Avtoref. kand. dissert. [The influence of operating conditions on reliability of bitumen-mineral coatings of highways in Northern Kazakhstan. PhD Abstract]. Moscow. 1972. 32 p. (rus)

24. Mohammed A. A., Morshed K. The effect of ageing on physical and chemical properties of asphalt cement. Iraqi Journal of Chemical and Petroleum Engineering. 2008. V. 9, No. 2. Pp. 9–15.

25. Pshenichnykh O. A., Skorik D. S. Opyt primeneniya dispersno-armirovannykh asfal'tobetonov v dorozhnom stroitel'stve [Experience of using dispersion hardened asphalt concretes in road construction]. Vestnik Donbasskoi natsional'noi akademii stroitel'stva i arkhitektury. 2020. No. 141. Pp. 121–127. (rus)

26. Alshakhvan A., Kalgin Yu. I. Uluchshenie strukturno-mekhanicheskikh svoistv teplogo asfal'tobetona metodom polimerno-dispersnogo armirovaniya [Improving structural and mechanical properties of warm asphalt concrete by polymer dispersion hardening]. Proektirovanie I stroitel'stvo dorog, metropolitenov, aerodromov, mostov i transportnykh tonnelei. 2021. No. 61. Pp. 53–61. (rus)

27. Pshenichnykh O. A. Deformatsionno-prochnostnye kharakteristiki dispersno-armirovannykh asfal'tobetonov [Deformation strength properties of dispersion hardened asphalt concrete]. Vestnik Donbasskoi natsional'noi akademii stroitel'stva i arkhitektury. 2020. No. 143. Pp. 41–44. (rus)

28. Merzlikin A. E., Gamelyak I. P. Ispytaniya konstrukcij dorozhnyh odezhd dlya ocenki effektivnosti primeneniya dispersno armirovannogo asfal'tobetona [Effectiveness of pavement structures of dispersion hardened asphalt concrete]. Trudy Soyuzdornii. Konstruirovanie, raschet i ispy`tanie dorozhnykh odezhd. 1990. Pp. 17–25. (rus)

29. Smith R. D. Laboratory testing of fabric interlayer for asphalt concrete paving: Interim report. Journal of the Transportation Research Board. 1983. Nо. 916. Pp. 6−18.

30. Tessoneau H. Revement tris mince mediflex en couche de voulement sur absur troisiene voie macon nord. Revue Generale des Routes et des Aerodromes. 1988. V. 62. No. 650. P. 77–78.

31. Pinaud Y., Hintzi J., Poirier J., Chanseaulme M. Le Rugoflex. Une experience de dix ans. Revue Generale des Routes et des Aerodromes. 1988. No. 649. Pp. 61–64.

32. Lukashevich V. N. Uvelicheniya sroka sluzhby asfal'tobetonnykh pokrytii za schet dvukhstadiinogo vvedeniya organicheskikh vyazhushchikh v protsesse proizvodstva asfal'tobetonnykh smesei [Service life increase of asphalt pavements by two-stage introduction of organic binders in asphalt concrete production]. Stroitel'nye materialy. 2003. No. 1. Pp. 24−25. (rus)

33. Florovskaya V. N., Ovchinnikova L. I. Lyuminescentnaya mikroskopiya bituminoznyx veshhestv [Luminescence microscopy of bituminous substances]. Moscow, 1970. 80 p. (rus).

34. Wertz J. E., Bolton J. R. Teoriya i prakticheskie prilozheniya primeneniya metoda EPR [Electron spin resonance: Elementary theory and practical applications]. Moscow: Mir, 1975. 368 p. (transl. from Engl.)

35. Unger F. G., Andreeva L. N. Fundamental'nye aspekty himii nefti. Priroda smol i asfal'tenov [Fundamental aspects of oil chemistry. The nature of resins and asphaltenes]. Novosibirsk: Nauka, 1995. 192 p. (rus)

36. Zhelezko E. P., Pechenyj B. G. O kinetike obrazovaniya i rekombinacii svobodny`x radikalov v bitumax [Kinetics of formation and recombination of free radicals in bitumen]. Trudy Soyuzdornii. 1970. No. 46. Pp. 137–142. (rus)


Review

For citations:


Lukashevich V.N., Lukashevich O.D., Mokshin R.I. Manufacture-affected asphaltene genesis in dispersion hardened bitumen-mineral compositions. Vestnik Tomskogo gosudarstvennogo arkhitekturno-stroitel'nogo universiteta. JOURNAL of Construction and Architecture. 2022;24(5):178-188. (In Russ.) https://doi.org/10.31675/1607-1859-2022-24-5-178-188

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