Silicate brick production using anhydrite raw material

Purpose: The aim of this work is to substantiate recycling of anhydrite raw materials for the production of silicate products and the development of methods for preparing source materials, compositions and process modes.
Methodology/approach: Selection and research of basic materials, methods of their preparation for the production of silicate products; justification of process methods and assessment of quality parameters of materials with the required properties.
Research findings: The possibility of utilizing acid fluoride during the synthesis of calcareous-siliceous binder used to produce silicate bricks during autoclave processing. The obtained sand-lime brick samples possess the following physical and mechanical properties: 1750 to 1900 kg/m³ average density, 10 to 12.5 MPa compressive strength, 16 or 17 % water absorption. The samples meet the requirements for sand-lime bricks, namely strength, density, water absorption and correspond to grades 100 and 125.
Practical implications: The process modes of autoclaving are detected and the main operational characteristics of sand-lime brick are determined. Methods proposed for preparing raw materials and process conditions of silicate wall materials allow solving environmental problems and saving natural limestone raw materials.
Novelty: Sand-lime brick production is based on anhydrite raw materials; suggested dependencies make it possible to control the composition and properties of silicate materials.

1. Khavkin L.M. Sand-lime brick technology. Moscow: Stroiizdat, 1982. 384 p. (In Russian)

2. Skripnikova N.K., Yur'ev I.Yu. Sand-lime brick technology Integrated use of ash and slag waste from the Tomsk region to produce various types of building materials. Vestnik of Tomsk State University of Architecture and Building. 2013; 2 (39): 245−249. (In Russian)

3. Kuznetsov L.V., Men'shikova T.N. Decorative sand-lime brick with oxygen-converter production sludge. Stroitel'nye materialy. 2007; 10: 18−19. (In Russian)

4. Lesovik V.S. Genetic basis of energy saving in the building materials industry. Izvestiya vysshikh uchebnykh zavedenii. Stroitel'stvo. 1994; 7−8: 96−100. (In Russian)

5. Semenov A.A. Market analysis of sand-lime brick in Russia. Stroitel'nye materialy. 2010; 9: 4−5. (In Russian)

6. Kuznetsova G.V. Steaming sand-lime brick in autoclave. Stroitel'nye materialy. 2015; 10: 8−18. (In Russian)

7. Anikanova A.L., Volkova O.V., Kudyakov A.I., Kurmangalieva A.I. Activated composite fluoride binder. Stroitel'nye materialy. 2019; 1−2: 36−42. (In Russian)

8. Kudyakov A.I., Anikanova L.A., Redlikh V.V. Composite binding acid fluoride materials for fencing. Vestnik of Tomsk State University of Architecture and Building. 2012; 1 (34): 106−111. (In Russian)

9. Anikanova L.A., Kudyakov A.I., Volkova O.V. Wall and finishing materials using acid fluoride. Trudy Bratskogo gosudarstvennogo universiteta. Estestvennye i inzhenernye nauki. 2015; 1: 230–234. (In Russian)

10. Volodchenko A.N., Lesovik V.S. Silicate autoclave materials using nanodispersed raw materials. Stroitel'nye materialy. 2008; (11): 42−45. (In Russian)

11. Kuznetsova G.V. Steaming sand-lime brick in autoclave. Stroitel'nye materialy. 2015; 10: 8−18. (In Russian)

12. Yakovlev G.I., Kodolov V.I. Liquid-phase sintering of acid fluoride in synthesis of gypsumceramic materials. Khimiya i khimicheskaya tekhnologiya. 1999; 42 (1): 97−101. (In Russian)

13. Anikanova L.A., Kudyakov A.I., Nikitina O.V. Influence of polymersilicate liquid on water resistance of composite fluorohydrite binders. In: Proc. Weimar Gypsum Conference, March 26−27. Weimar, 2014. Pp. 183−190.

14. Anikanova L.A. Recycled gypsum-containing raw materials in building material production. In: Proc. 7th Int. Sci. Conf., Tomsk, 2017. Pp. 31−34. (In Russian)

15. Sulimova E.V., Lapidus M.A., Garkavi M.S. Issues of hardening of anhydrite binders. Stroitel'nye materialy. 1993; (7): 12–17. (In Russian)